Polyelectrolyte-functionalized ionic liquid for electrochemistry in supporting electrolyte-free aqueous solutions and application in amperometric flow injection analysis

As a green process, electrochemistry in aqueous solution without a supporting electrolyte has been described based on a simple polyelectrolyte-functionalized ionic liquid (PFIL)-modified electrode. The studied PFIL material combines features of ionic liquids and traditional polyelectrolytes. The ionic liquid part provides a high ionic conductivity and affinity to many different compounds. The polyelectrolyte part has a good stability in aqueous solution and a capability of being immobilized on different substrates. The electrochemical properties of such a PFIL-modified electrode assembly in a supporting electrolyte-free solution have been investigated by using an electrically neutral electroactive species, hydroquinone ( HQ) as the model compound. The partition coefficient and diffusion coefficient of HQ in the PFIL film were calculated to be 0.346 and 4.74 X 10(-6) cm(2) s(-1), respectively. Electrochemistry in PFIL is similar to electrochemistry in a solution of traditional supporting electrolytes, except that the electrochemical reaction takes place in a thin film on the surface of the electrode. PFILs are easily immobilized on solid substrates, are inexpensive and electrochemically stable. A PFIL-modified electrode assembly is successfully used in the flow analysis of HQ by amperometric detection in solution without a supporting electrolyte.

ELECTROANALYTICAL FLOW MEASUREMENTS

A review based on 94 cited original papers describes recent achievements in application of different electrochemical detection in flow analysis, injection techniques of flow analysis, liquid chromatography and capillary electrophoresis.

超燃燃烧室一维流场分析模型的研究

对公开发表的用于超声速燃烧流场分析的几种一维模型进行了研究，指出了其中存在的问题，研究结果表明：基于实验静压数据的一维模型，若不借助必要的流场测量数据或分析结果，或借助于经验性的处理方法，单靠一维假设，无法获得较为完整的一维流场分析结果。改进后的一维模型降低了数据处理过程中的不确定性，提高了对一般情况的适应能力。用编制的计算程序SSC-2对两组典型的超燃燃烧室壁面静压实验数据进行了演算，取得了燃烧室出口总压恢复系数的计算值与测量值基本一致的好结果。

多级安全OS与DBMS模型的信息流及其一致性分析

数据库安全与操作系统安全密不可分,如果多级安全DBMS的安全策略不违反OS的安全策略,那么可以使用多级安全OS的安全机制来实现DBMS的部分安全功能,如强制访问控制.信息流分析使我们能更好地理解安全策略的意义和内容.该文给出了多级安全OS模型和以该模型为基础的多级安全DBMS模型,首次详细分析了它们在强制访问控制策略下的信息流集合.经过主客体的映射后,证明了数据库与操作系统的信息流集合是一致的,这个结论保证了利用OS的机制来实现DBMS的强制访问控制的合理性.

移动对象数据库模型、查询语言及实时交通流分析

提出一种移动对象数据库模型——Dynamic Transportation Network Based Moving Objects Database(简称DTNMOD),并给出了DTNMOD中基于移动对象时空轨迹的网络实时动态交通流分析方法.在DTNMOD中,交通网络被表示成动态的时空网络,可以描述交通状态、拓扑结构以及交通参数随时间的变化过程;网络受限的移动对象则用网络移动点表示.DTNMOD模型包含了完整的数据类型和查询操作的定义,因此可以在任何可扩充数据库(如PostgreSQL或SECONDO)中实现,从而得到完整的数据库模型和查询语言.为了对相关模型的性能进行比较与分析,基于PostgreSQL实现了一个原型系统并进行了一系列的实验.实验结果表明,DTNMOD提供了良好的区域查询及连接查询性能.

JUTA:一个Java自动化单元测试工具

描述了一个Java自动化的单元测试工具JUTA.JUTA首先调用工具Soot解析单个Java方法的源码,并将源码解析成一个控制流图.在此基础上,采用符号执行的方法分析控制流图上的路径.工具能够自动地产生满足覆盖率标准的程序的测试用例.这种方法产生的所有测试用例都是可执行的,并且一般来说具有较小的测试用例数.如果用户能够合理地给出描述程序错误的断言,框架JUTA能够自动地检查源码中部分特定类型的错误.实验结果表明工具对Java单元代码的动态测试和静态测试均能在可接受的时间内给出有效的结果.

incremental learning of triadic plsa for collaborative filtering

Beijing University of Technology (BJUT); Beijing Municipal Lab of Brain Informatics; Chinese Society of Radiology; National Natural Science Foundation of China (NSFC); State Administration of Foreign Experts Affairs

一种五自由度机电测控系统的设计与实现

文章提出了一种基于五自由度机电系统的测控系统设计方法,并从机械系统构成、测控系统结构及软硬件设计方面论述了系统实现技术。针对系统特定的功能要求,文章详细介绍了位姿组合测量和各位姿自由度控制的测控方法,并应用模块化设计和数据流分析方法进行软硬件设计。通过实验进行系统特性分析,得到运行参数指标。实验证明这种设计方法和实现技术合理可行。

地下水位上升造成的黄土远程滑坡形成机理与数值模拟研究

Based on field survey, laboratory testing and numerical modeling, engineering characteristics of undisturbed loess and the mechanism of long-runout loess landslides caused by underground water level rise, as well as the formation conditions and spatial distribution of landslides, are systematically studied and analyzed. Loess landslides at south Plateau of Jingyang County are mainly classified as flowslide, slide and fall. Flowslide is the main type characteristic of high velocity, long runout and multi-stages. The steep relief composed of loose structured loess-old aged soil serials and the rise of groundwater table are the predominant conditions for landslides in the study area. To study loess mechanic poperties and loess landslides mechanisims, isotropically and anisotropically consolidated undrained compression(ICU and ACU) tests and constant-deviator-drained compression (CQD) tests were carried out on undisturbed samples. The results of undrained compression tests performed at the in-situ stress level show that the soils are of consistently strain-softening in the stress-strain relations and cause high excess pore pressure. The steady-state line and the potential region of instability are obtained from ICU and ACU test results. A necessary condition for liquefaction is that the soil state initially lies in or is brought into the potential instability region. In addition, a strong strain-softening model is also formed. CQD tests demonstrate that the mobilized friction angle is far less than the steady-state angle and that the soil experiences undrained contractive failure suddenly at very small strains when its stress path during drained loading tries to cross the potential instability region，thus validates the proposed instability region. Based on the location of the region of potential instability and the stress state of slope soil, a method of static liquefaction analysis is proposed for loess landslides caused by rise in groundwater table. Compared with other liquefaction analysis methods, this method overcomes the limitations inherent in conventional slope stability method and undrained brittleness index method. Triaxial tests composed of constant water content (CW) and wetting tests at constant deviator stress are performed on undisturbed unsaturated samples. The stress-strain relation of CW tests takes on strain-hardening behavior; The results of wetting tests at constant deviator stress designed to study the mechanics of failure of unsaturated loess caused by an increase in the degree of saturation (wetting) shows that a contractive failure occurs in the undisturbed samples. On the basis of the above triaxial test results, the initiation of static liquefaction is presented for long-runout loess landslides caused by rise in groundwater table, that is, the loess slope soil gradually transfer from unsaturated to saturated state under the infiltration of irrigation. A contractive failure occurs in the local region at very small strain by increasing the pore-water pressure at constant deviator stresses under drained conditons. It is the contractive failrue resulting from rise of pore pressure that leads to high excess pore pressure in the neighbour soil which reduces shear resistance of soil. The neighbour soils also fail due to the rapid increase in pore-water pressure. Thus a connected failure surface is developed quickly and a flowslide occurs. Based on the saturated-unsaturated seepage theory, transient seepage is computed using the finite element method on loess slope under groundwater table rise. Pore-water pressure distribution for every time step after irrigation are obtained. The phreatic surface in the slope increases with the groundwater table. Pore-water pressure distribution within 8m above the phreatic surface changes very quickly，but the water content and pore water pressure in the region ranging from 8m above the phreatic surface up to ground surface is almost not affected and the matric suction usually is kept at 100～120 kPa. Based on the results of laboratory tests and seepage flow analysis, the development process of loess landslide is modeled considering groundwater table rise. The shearing plastic zone first occurs at the slope toe where the soil is soaked for long term during rise in groundwater table. As irrigation continues, the shearing plastic zone gradually extends to the interior soils, with the results that the tensile plastic zone occurs at the slope crown. As time goes on, both the shearing plastic zone and tensile plastic zone continue to extend. Then a connected plastic zone is formed and fowslide occurs. In comparision to laboratory test results, the results of numerical simulation quite well verify the presented mechanism of static liquefaction of long-runout loess landslides caused by rise in groundwater table.

Numerical Analysis on Intermittent Flow in a Longitudinal Section of Bingham Fluid along a Slope

The transition process of intermittent flow in a longitudinal section of Bingham fluid from initial distribution to fully developed state was numerically investigated in this paper. The influences of slope dimensionless runoff Q* and viscosity μ0* on the dimensionless surge speed U* were also presented in a wide range of parameters. By one typical example, the intermittent flow possessed wave characteristics and showed a supercritical flow conformation for a fully developed flow. The distributions of gravity and bed drag along the flow path and the velocity distribution of flow field were also analyzed.

Numerical Analysis of the Effects of Free-Stream Thermo-Chemical State on the Test Model Flow Field in High-Enthalpy Tunnel

The effects of the free-stream thermo-chemical state on the test model flow field in the high-enthalpy tunnel are studied numerically. The properties of the free-stream, which is in thermo-chemical non-equilibrium, are determined by calculating the nozzle flow field. A free-stream with total enthalpy equal to the real one in the tunnel while in thermo-chemical equilibrium is constructed artificially to simulate the natural atmosphere condition. The flow fields over the test models (blunt cone and Apollo command capsule model) under both the non-equilibrium and the virtual equilibrium free-stream conditions are calculated. By comparing the properties including pressure, temperature, species concentration and radiation distributions of these two types of flow fields, the effects of the non-equilibrium state of the free-stream in the high-enthalpy shock tunnel are analyzed.